The advantages of covalently attaching organometallic catalysts to a carbon black support: recyclable Rh(i) complexes that deliver enhanced conversion and product selectivity

Author:

Tregubov Andrey A.1234,Walker D. Barney1234,Vuong Khuong Q.12345,Gooding J. Justin1234,Messerle Barbara A.1234

Affiliation:

1. School of Chemistry

2. The University of New South Wales

3. Sydney 2052

4. Australia

5. Institute of Chemical and Engineering Sciences

Abstract

A bidentate Rh(i) coordination complex was covalently anchored to a carbon black support. The resultant hybrid catalyst was found to be active for both hydroamination and dihydroalkoxylation reactions and was readily recycled.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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