Controlling the europium oxidation state in diopside through flux concentration

Author:

Górecka N.1,Leśniewski T.1ORCID,Mahlik S.1ORCID,Łapiński M.2,Tsai Y.-T.3,Bielicka-Giełdoń A.4ORCID,Szczodrowski K.1ORCID

Affiliation:

1. Institute of Experimental Physics, Faculty of Mathematics, Physics, and Informatics, University of Gdańsk, Wita Stwosza 57, 80-308 Gdańsk, Poland

2. Institute of Nanotechnology and Materials Engineering, Gdansk University of Technology, Gabriela Narutowicza 11/12, 80-233 Gdansk, Poland

3. Research Center for Applied Sciences, Academia Sinica, Taipei 11529, Taiwan

4. Faculty of Chemistry, University of Gdansk, Wita Stwosza 63, 80-308 Gdansk, Poland

Abstract

The reduction of lanthanides (Ln3+) incorporated into alkali earth sites in a matrix, , requires the creation of electron donating defects, e.g., and elimination of charge compensation defects, e.g. V′′Me, from the vicinity of the .

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

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