Spin polarization assisted facile C–H activation by an <i>S</i> = 1 iron(<scp>iv</scp>)–bisimido complex: a comprehensive spectroscopic and theoretical investigation-Reference-Cited by-同舟云学术

Spin polarization assisted facile C–H activation by an S = 1 iron(iv)–bisimido complex: a comprehensive spectroscopic and theoretical investigation

Published:2023 Issue:11 Volume:14 Page:2808-2820
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xiong Jin¹^ORCID,Liu Qing²^ORCID,Lavina Barbara³⁴^ORCID,Hu Michael Y.³^ORCID,Zhao Jiyong³^ORCID,Alp Esen E.³,Deng Liang²^ORCID,Ye Shengfa⁵^ORCID,Guo Yisong¹^ORCID

Affiliation:

1. Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania, 15213, USA

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P. R. China

3. Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois, 60439, USA

4. Center for Advanced Radiation Sources, University of Chicago, Chicago, Illinois, 60439, USA

5. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

Abstract

A spectroscopic and computational study reveals that bulky electron-withdrawing imido substituents stabilize a rare S = 1 iron(iv)–bisimido complex with a pseudo doubly degenerate ground electronic structure, accounting for its facile HAT reactivity.

Funder

National Natural Science Foundation of China

National Institute of General Medical Sciences

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06273A

Reference88 articles.

1. Mid- to high-valent imido and nitrido complexes of iron