Oxidative two-way regiocontrolled coupling of 3-methoxycarbonylcatechol and indoles to arylindoles-Reference-Cited by-同舟云学术

Oxidative two-way regiocontrolled coupling of 3-methoxycarbonylcatechol and indoles to arylindoles

Published:2022 Issue:93 Volume:58 Page:12935-12938
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sawama Yoshinari¹^ORCID,Kuwata Shoko²,Mae Miyu¹,Udagawa Taro³^ORCID,Akai Shuji¹^ORCID,Sajiki Hironao²^ORCID

Affiliation:

1. Graduate School of Pharmaceutical Sciences, Osaka University, 1-6, Yamada-oka, Suita, Osaka 565-0871, Japan

2. A Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4-Daigaku-nishi, Gifu 501-1196, Japan

3. Gifu University, 1-1 Yanagido, Gifu 501-1193, Japan

Abstract

3-Methoxycarbonylcatechol underwent two-way regiocontrolled coupling of indoles and ortho-benzoquinone intermediate, resulting from PIDA oxidation, with or without BF3·Et2O. DFT calculations confirmed the obtained regioselectivities.

Funder

Japan Society for the Promotion of Science

Japan Agency for Medical Research and Development

Research Foundation for the Electrotechnology of Chubu

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04843D

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5. Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

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