Placing gold on a π<sup>+</sup>-surface: ligand design and impact on reactivity-Reference-Cited by-同舟云学术

Placing gold on a π⁺-surface: ligand design and impact on reactivity

Published:2023 Issue:2 Volume:14 Page:277-283
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Wei-Chun¹^ORCID,Gabbaï François P.¹^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, College Station, TX 77843, USA

Abstract

Non-covalent interactions between the AuCl moiety of a newly synthesised complex and the π+ surface of the adjacent xanthylium cation elevate the carbophilic reactivity of the gold center.

Funder

National Science Foundation

American Chemical Society

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05574K

Reference50 articles.

1. Chemistry and Optoelectronic Properties of Stacked Supramolecular Entities of Trinuclear Gold(I) Complexes Sandwiching Small Organic Acids

2. Alteration of the Aurophilic Interactions in Trimeric Gold(I) Compounds through Charge Transfer. Behavior of Solvoluminescent Au3(MeNCOMe)3 in the Presence of Electron Acceptors

3. External heavy-atom effect of gold in a supramolecular acid–base π stack

4. Photophysics of supramolecular binary stacks consisting of electron-rich trinuclear Au(I) complexes and organic electrophiles

5. Gold⋯π aryl interactions as supramolecular synthons

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