Orientation and morphology control in acid-catalyzed covalent organic framework thin films

Author:

Bhagwandin Dayanni D.12ORCID,Page Kirt A.123ORCID,Tran Ly D.12,Yao Yao4,Reidell Alexander12ORCID,Muratore Christopher5,Fang Qiyi67,Ruditskiy Aleksey12,Hampton Cheri M.12ORCID,Kennedy W. Joshua1ORCID,Drummy Lawrence F.1,Zhong Yu7,Marks Tobin J.4ORCID,Facchetti Antonio48ORCID,Lou Jun6ORCID,Koerner Hilmar1,Baldwin Luke A.1ORCID,Glavin Nicholas R.1ORCID

Affiliation:

1. Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433, USA

2. UES, Inc., Beavercreek, Ohio 45432, USA

3. Cornell High Energy Synchrotron Source, Cornell University, Ithaca, New York 14853, USA

4. Department of Chemistry and the Materials Research Center, Northwestern University, Sheridan Road, Evanston, IL 60208, USA

5. Department of Chemical and Materials Engineering, University of Dayton, Dayton, Ohio 45469, USA

6. Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005, USA

7. Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, USA

8. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA

Abstract

Wafer-scale, high quality crystalline covalent organic framework thin films were synthesized via a liquid–liquid interfacial synthesis approach with strict morphological and orientation control.

Funder

Air Force Office of Scientific Research

Air Force Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

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