Synthesis of P,P-bidentate caged phosphines via tungsten pentacarbonyl-promoted cycloaddition reactions of 1-alkyl-1,2-diphospholes

Author:

Zagidullin Almaz A.1ORCID,Ganushevich Yulia S.2ORCID,Korchagin Denis V.3ORCID,Lönnecke Peter4ORCID,Hey-Hawkins Evamarie4ORCID,Miluykov Vasili A.1ORCID

Affiliation:

1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088, Kazan, Russia

2. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov St., Moscow 119334, Russia

3. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Chernogolovka, Moscow Region 142432, Russia

4. Institute of Inorganic Chemistry, Leipzig University, Leipzig 04103, Germany

Abstract

Utilizing the W(CO)5 group as a promoter and [4+2] cycloaddition reactions, 1-alkyl-1,2-diphospholes were converted to P,P-bidentate phosphines.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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