Electrocatalytic N2-to-NH3 conversion using oxygen-doped graphene: experimental and theoretical studies

Author:

Wang Ting12345ORCID,Xia Li12345,Yang Jia-Jia6789,Wang Huanbo1011129,Fang Wei-Hai6789,Chen Hongyu12345ORCID,Tang Dianping1314151617ORCID,Asiri Abdullah M.1819202122ORCID,Luo Yonglan12345ORCID,Cui Ganglong6789ORCID,Sun Xuping12345ORCID

Affiliation:

1. Chemical Synthesis and Pollution Control

2. Key Laboratory of Sichuan Province

3. School of Chemistry and Chemical Engineering

4. China West Normal University

5. Nanchong 637002

6. College of Chemistry

7. Beijing Normal University

8. Beijing 100875

9. China

10. School of Environment and Resource

11. Southwest University of Science and Technology

12. Mianyang 621010

13. Key Laboratory for Analytical Science of Food Safety and Biology (MOE & Fujian Province)

14. State Key Laboratory of Photocatalysis on Energy and Environment

15. Department of Chemistry

16. Fuzhou University

17. Fuzhou 350108

18. Chemistry Department

19. Faculty of Science & Center of Excellence for Advanced Materials Research

20. King Abdulaziz University

21. Jeddah 21589

22. Saudi Arabia

Abstract

Oxygen-doped graphene acts as an efficient electrocatalyst for conversion of N2 to NH3 in 0.1 M HCl, achieving a large NH3 yield of 21.3 μg h−1 mgcat.−1 and a high FE of 12.6%.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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