In situ interphase engineering for all-solid-state Li batteries: a case study on the LiNi0.5Mn1.5O4/Li0.33La0.55TiO3 composite cathode guided by ab initio calculations

Author:

Lin Che-an1ORCID,Ihrig Martin2ORCID,Kung Kuan-chen1,Chen Hsiang-ching1,Finsterbusch Martin3ORCID,Guillon Olivier3ORCID,Lin Shih-kang1456ORCID

Affiliation:

1. Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan

2. Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan

3. Institute of Energy and Climate Research – Materials Synthesis and Processing (IEK-1), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany

4. Hierarchical Green-Energy Materials (Hi-GEM) Research Center, National Cheng Kung University, Tainan 70101, Taiwan

5. Program on Smart and Sustainable Manufacturing, Academy of Innovative Semiconductor and Sustainable Manufacturing, National Cheng Kung University, Tainan 70101, Taiwan

6. Core Facility Center, National Cheng Kung University, Tainan 70101, Taiwan

Abstract

Doping-induced artificial interphase formation in oxide-based composite cathodes is demonstrated to simultaneously improve sinterability and interfacial stability, which are the main bottlenecks of oxide-based all-solid-state Li batteries.

Funder

Bundesministerium für Bildung und Forschung

National Science and Technology Council

Ministry of Education

Deutscher Akademischer Austauschdienst

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

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