Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtCCCCCCCC]mPtX segments; iterative syntheses and functionalization for measurements of single molecule properties
Author:
Affiliation:
1. Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials
2. Friedrich-Alexander-Universität Erlangen-Nürnberg
3. 91054 Erlangen
4. Germany
5. Department of Chemistry
6. Texas A&M University
7. College Station
8. USA
Abstract
The title complexes are accessed from platinum chloride and Z(CC)2SiMe3 (Z = Me3Sn, H) building blocks via oxidative homocouplings and cross couplings.
Funder
Deutsche Forschungsgemeinschaft
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00870E
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2. Carbon in One Dimension: Structural Analysis of the Higher Conjugated Polyynes
3. Transition Metal Complexes Containing All-Carbon Ligands
4. Iron versus Ruthenium: Clarifying the Electronic Differences between Prototypical Mixed-Valence Organometallic Butadiyndiyl Bridged Molecular Wires
5. Reactivity of Polyynes: Complex Molecules from Simple Carbon Rods
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