Theoretical insights into structure, bonding, reactivity and importance of ion-pair interactions in Kirby's tetrafluoroboric acid salts of twisted amides-Reference-Cited by-同舟云学术

Theoretical insights into structure, bonding, reactivity and importance of ion-pair interactions in Kirby's tetrafluoroboric acid salts of twisted amides

Published:2015 Issue:128 Volume:5 Page:105668-105677
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Pandey Krishna K.¹²³⁴

Affiliation:

1. School of Chemical Sciences

2. D. A. University Indore

3. Indore 452 017

4. India

Abstract

The hydrolysis of amide 1 is more exothermic and is more favorable than amides 2 and 3 with bridgehead methyl.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA22792E

Reference65 articles.

1. A. Greenberg , The Amide Linkage as a Ligand-Its Properties and the Role of Distortion, in The Amide Linkage: Structural Significance in Chemistry, Biochemistry, and Materials Science, ed. A. Greenberg, C. M. Breneman and J. F. Liebman, Wiley, New York, 2000

2. The pH-Rate Profile for the Hydrolysis of a Peptide Bond

3. Structures and energetics of two bridgehead lactams and their N- and O-protonated forms: an ab initio molecular orbital study

4. Small and Medium-Sized Bridgehead Bicyclic Lactams: A Systematic ab Initio Molecular Orbital Study

5. Alkaline Hydrolysis of Amide Bonds: Effect of Bond Twist and Nitrogen Pyramidalization

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