Activation of O2 across a C(sp3)–C(sp3) bond-Reference-Cited by-同舟云学术

Activation of O₂ across a C(sp³)–C(sp³) bond

Published:2022 Issue:19 Volume:58 Page:3122-3125
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kumar Rahul¹^ORCID,Richter Stefan²,Maity Suvendu³,Sarkar Pallavi⁴,Chrysochos Nicolas¹^ORCID,Pati Swapan K.⁴^ORCID,Ghosh Prasanta³^ORCID,Schulzke Carola²^ORCID,Jana Anukul¹^ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad-500046, Telangana, India

2. Institut für Biochemie, Universität Greifswald, Felix-Hausdorff-Straße 4, D-17489 Greifswald, Germany

3. Department of Chemistry, Ramakrishna Mission Residential College, Narendrapur, Kolkata-700103, India

4. Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560064, India

Abstract

Molecular dioxygen is activated across the C(sp3)–C(sp3) bond of a piperazine derivative. This unprecedented reaction proceeds without any catalyst and at ambient condition yielding a 8-membered cyclic organic peroxide.

Funder

Department of Atomic Energy, Government of India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00110A

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