A γ-cyclodextrin duplex connected with two disulfide bonds: synthesis, structure and inclusion complexes-Reference-Cited by-同舟云学术

A γ-cyclodextrin duplex connected with two disulfide bonds: synthesis, structure and inclusion complexes

Published:2015 Issue:10 Volume:13 Page:2980-2985
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Volkov Sergey¹²³,Kumprecht Lukáš¹²³,Buděšínský Miloš¹²³,Lepšík Martin¹²³,Dušek Michal⁴⁵⁶³,Kraus Tomáš¹²³

Affiliation:

1. Institute of Organic Chemistry and Biochemistry AS CR

2. 166 10 Prague 6

3. Czech Republic

4. Institute of Physics

5. AS CR

6. 182 21 Praha 8

Abstract

Oxidative dimerization of 6^I,6^V-disulfanyl-γ-cyclodextrin yields a duplex tubular structure with internal volume of ∼740 Å³ allowing formation of very stable inclusion complexes with medium to large organic molecules in water (K_a ∼ 10⁸ M⁻¹).

Funder

Czech Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02464H

Reference38 articles.

1. H. E. Dodziuk , Cyclodextrins and Their Complexes, Wiley-VCH, Wienheim, 2006

2. Binding Affinities of Host–Guest, Protein–Ligand, and Protein–Transition-State Complexes

3. Modified Cyclodextrins with Pendant Cationic and Anionic Moieties as Hosts for Highly Stable Inclusion Complexes and Molecular Recognition

4. Selectively functionalized cyclodextrins and their metal complexes

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