The first structurally characterised early main-group metal diazallyl complex; synthesis and crystal structure of LiCPh(NPh)2·NMe[(CH2)2NMe2]2
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930002423
Reference23 articles.
1. Lithiations of mercaptoamines containing NC(S)NH–,–NHC(S)S– and –NHC(S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
2. Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: synthesis and crystal structure of [naphthylN·NN·NC(S)]2Ba·3HMPA
3. Lithiation and dethiacarbonylation of a heterocyclic thioamide C6H4O·C(S)NH by reaction with solid Li2S in the presence of hexamethylphosphoramide: synthesis and crystal structure of [C6H4O·C(S)NLi·HMPA]2·C6H4(OH)NH2
4. Lithium- and dimethylaluminium-di-2-pyridyl-phosphides: the first metal diorganophosphides without a metal–phosphorus bond within a contact ion pair
5. Lewis base mediated rearrangements of alkali metal imides to η3-aza-allyl complexes: preparation and n.m.r. spectroscopic solution studies of [CH3CH2CH2C(H)C(But)N(H)·M·(HMPA)x]n(M = Li, x= 1; M = Na, x= 2)(HMPA = hexamethylphosphoramide)
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