Eleven-vertex polyhedral monocarbaplatinaborane chemistry. Structure and fluxionality of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930001261
Reference51 articles.
1. Organoruthenaborane chemistry. Part 7. Preparation, molecular structure, and nuclear magnetic resonance properties of eleven-vertex closo-type clusters: [2,4-Me2-1 -(pcym)-1,2,4-RuC2B8H8], [2,3-Me2-1 -(pcym)-1,2,3-RuC2B8H8], [1-(pcym)-1-RuB10H10] and some related species
2. Open cluster configurations of [1,1-(PPh3)2-1-H-1,2,4-IrC2B8H10] and other formally Wadian 24-electron 11-vertex species
3. An interesting low barrier to metal-ligand contrarotational fluxionality in closed 11-vertex [1,1-(PMe2Ph)2-1,2,3-PtC2B8H9X] compounds that is characterized by arachno .dblharw. nido geometric changes within the 10-vertex .eta.6-{C2B8H9X} ligand
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