Synthesis and application of methyl itaconate–anthracene adducts in configuration assignment of chiral secondary alcohols by 1H NMR

Author:

Rithchumpon Puracheth12ORCID,Intakaew Neeranuth123,Khamto Nopawit12ORCID,Yimklan Saranpong1ORCID,Nimmanpipug Piyarat1ORCID,Thavornyutikarn Praput1ORCID,Meepowpan Puttinan134ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Chiang Mai University, 239 Huay Kaew Road, Chiang Mai, 50200, Thailand

2. Graduate School, Chiang Mai University, 239 Huay Kaew Road, Chiang Mai 50200, Thailand

3. Center of Excellence for Innovation in Chemistry (PERCH-CIC), Faculty of Science, Chiang Mai University, 239 Huay Kaew Road, Chiang Mai 50200, Thailand

4. Center of Excellence in Materials Science and Technology, Faculty of Science, Chiang Mai University, 239 Huay Kaew Road, Chiang Mai 50200, Thailand

Abstract

Methyl itaconate–anthracene adducts (MIAs) were applied for the absolute configuration determination of chiral secondary alcohols by the 1H NMR technique including DFT calculation and X-ray crystallography.

Funder

National Research Council of Thailand

Center of Excellence for Innovation in Chemistry

Faculty of Science, Chiang Mai University

Graduate School, Chiang Mai University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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