Regioselective ring-opening of epoxides towards Markovnikov alcohols: a metal-free catalytic approach using abnormal N-heterocyclic carbene-Reference-Cited by-同舟云学术

Regioselective ring-opening of epoxides towards Markovnikov alcohols: a metal-free catalytic approach using abnormal N-heterocyclic carbene

Published:2022 Issue:68 Volume:58 Page:9540-9543
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

P. Sreejyothi¹,Sarkar Pallavi²,Dutta Supriti²,Das Arpan¹,Pati Swapan K.²^ORCID,Mandal Swadhin K.¹^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata, Mohanpur Campus, Nadia, 741246, West Bengal, India

2. Theoretical Sciences Unit, School of Advanced Materials (SAMat), Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore 560064, India

Abstract

This work highlights the metal-free Markovnikov ring-opening of epoxides using a nucleophilic abnormal N-heterocyclic carbene (aNHC).

Funder

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03549A

Reference29 articles.

1. K.Weissermel , H.-J.Arpe , C. R.Lindley and S.Hawkins , Industrial Organic Chemistry , John Wiley & Sons , 2008 , vol. 2

2. Anti-Markovnikov alcohols via epoxide hydrogenation through cooperative catalysis

3. Stereochemistry and Mechanism of Lithium Aluminum Hydride and Mixed Hydride Reduction of 4-t-Butylcyclohexene Oxide1

4. Reactivity versus Stability of Oxiranes under Palladium‐Catalyzed Reductive Conditions

5. Magnetically Separable Pd Catalyst for Highly Selective Epoxide Hydrogenolysis under Mild Conditions

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, characterization and stability of phosphonium phenolate zwitterions derived from a (diphenylphosphino)phenol derivative and oxiranes;Monatshefte für Chemie - Chemical Monthly;2024-05-08

2. Highly Selective and Practical Iron‐Catalyzed Formal Hydrogenation of Epoxides to Primary Alcohols Using Formic Acid;European Journal of Organic Chemistry;2023-03-22