Sourcing, thermodynamics, and ring-opening (co)polymerization of substituted δ-lactones: a review

Author:

McMichael Peter1,Schultze Xavier2,Cramail Henri1ORCID,Peruch Frédéric1ORCID

Affiliation:

1. Université de Bordeaux, CNRS, Bordeaux INP, LCPO, UMR 5629, 33600 Pessac, France

2. L'Oréal Recherche et Innovation, 1 avenue Eugène Schueller, 93600, Aulnay-sous-Bois, France

Abstract

Substituted δ-lactones are mostly biobased monomers with unfavorable to intermediate thermodynamic parameters. Nevertheless, they can lead to the synthesis of (co)polyesters by ring-opening (co)polymerization mediated by either organocatalysis or metal-based catalysis.

Funder

Fondation L'Oréal

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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