Photo- and thermo-induced spin crossover in a cyanide-bridged {MoV2FeII2} rhombus molecule

Author:

Mondal Abhishake12345,Li Yanling12345,Chamoreau Lise-Marie12345,Seuleiman Mannan12345,Rechignat Lionel6789,Bousseksou Azzedine6789,Boillot Marie-Laure101112,Lescouëzec Rodrigue12345

Affiliation:

1. Sorbonne Universités

2. UPMC Univ. Paris 06

3. UMR 8232

4. Paris, France

5. CNRS

6. Laboratoire de Chimie de Coordination

7. CNRS UPR-8241

8. Route de Narbonne

9. 31077 Toulouse cedex 04, France

10. Institut de Chimie Moléculaire et des Matériaux d'Orsay

11. UMR CNRS 8182

12. 91405 Orsay cedex, France

Abstract

The self-assembly of [MoV(CN)8]3− and [FeII(bik)2(S)2]2+ affords a cyanide-bridged {MoV2FeII2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperatures and exhibits thermo-induced spin crossover near ambient temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference21 articles.

1. Photoinduced Magnetization of a Cobalt-Iron Cyanide

2. Laser-Induced Ferroelectric Structural Order in an Organic Charge-Transfer Crystal

3. One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature

4. Spin Crossover in Transition Metal Compounds I-III , ed. P. Gütlich and H. A. Goodwin , Top. Curr. Chem., Springer , Heidelberg , 2004 , vol. 233–235

5. Spin-Crossover Materials, Properties and Applications , ed. M. A. Halcrow , Wiley , Chichester , 2013

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3