Synthesis and electronic properties of A3B-thienyl porphyrins: experimental and computational investigations

Author:

Kumar Poomani Ram1234,Britto Neethinathan Johnee56784,Kathiravan Arunkumar9104ORCID,Neels Antonia1112131415,Jaccob Madhavan56784ORCID,Mothi Ebrahim M.1234ORCID

Affiliation:

1. Centre for Scientific and Applied Research

2. PSN College of Engineering and Technology

3. Tirunelveli 627 152

4. India

5. Department of Chemistry & Computational Chemistry Laboratory

6. Loyola Institute of Frontier Energy (LIFE)

7. Loyola College

8. Chennai – 600 034

9. Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology

10. Chennai 600 062

11. Center for X-ray Analytics, Empa – Swiss Federal Laboratories for Materials Science and Technology

12. Überlandstrasse 129

13. 8600

14. Dübendorf

15. Switzerland

Abstract

A facile synthesis ofmeso-thienyl porphyrins containing a phenyl substituent allows fine tuning of the frontier orbitals to suit applications in DSSC and photomedicine.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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