The mystery of Ph<sub>3</sub>PS revealed in magic-size Ag–S cluster nucleation-Reference-Cited by-同舟云学术

The mystery of Ph₃PS revealed in magic-size Ag–S cluster nucleation

Published:2022 Issue:45 Volume:51 Page:17145-17149
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wu Wei-Hong¹,Gao Yu-Quan¹,Lin Yu-Fei¹,Yuan Yun-Yue¹,Zhan Cai-Hong¹^ORCID,Jiang Zhan-Guo¹^ORCID

Affiliation:

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, College of Chemistry and Life Sciences, Zhejiang Normal University, No. 688, Yingbin Avenue, Jinhua, Zhejiang, 321004, China

Abstract

PPh3S was employed to direct the regulation of {Ag32S3} cluster by slowing down the kinetic process of nucleation. The process that Agn(CCBut)m and traces of water induces breakage of PS from [Ag2(Ph3PS)4]2+ to generate {Ag32S3} was established.

Funder

Zhejiang Normal University

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT03418B

Reference28 articles.

1. Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles

2. Quantum Mechanical Studies of Large Metal, Metal Oxide, and Metal Chalcogenide Nanoparticles and Clusters

3. The Role of Ligands in the Chemical Synthesis and Applications of Inorganic Nanoparticles

4. Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials

5. Two-Dimensional Colloidal Nanocrystals

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