Solvent-mediated single-crystal-to-single-crystal transformation from a dimeric to tetrameric copper(i) complex based on a substituted pyridine derived from a Diels

Solvent-mediated single-crystal-to-single-crystal transformation from a dimeric to tetrameric copper(i) complex based on a substituted pyridine derived from a Diels–Alder adduct

Published:2017 Issue:15 Volume:41 Page:7598-7604
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Chan Tai-Wei¹²³,Zhan Shun-Ze⁴⁵⁶⁷,Razali Mohd. R.¹²³^ORCID

Affiliation:

1. School of Chemical Sciences

2. Universiti Sains Malaysia

3. Malaysia

4. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials

5. Guangdong Province

6. Shantou University

7. P. R. China

Abstract

A solution of [Cu₂I₂L₂(MeCN)₂] (1) in dichloromethane (DCM) assisted the removal of MeCN and N-(4-pyridinyl)-9,10-dihydroethanoanthracene-11,12-dicarboximide (L) from the crystal of 1, leading to an unprecedented SCSC transformation.

Funder

Universiti Sains Malaysia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ01552F

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