Unique binding behaviour of water-soluble polycationic oxacalix[4]arene tweezers towards the paraquat dication

Author:

Manganaro Nadia1234,Lando Gabriele1234,Gargiulli Claudia1234,Pisagatti Ilenia1234,Notti Anna1234,Pappalardo Sebastiano1564,Parisi Melchiorre F.1234,Gattuso Giuseppe1234

Affiliation:

1. Dipartimento di Scienze Chimiche

2. Università di Messina

3. 98166 Messina

4. Italy

5. Università di Catania

6. 95125 Catania

Abstract

Water-soluble polycationic oxacalix[4]arene molecular tweezers recognize the paraquat dication under pH control, balancing repulsive electrostatic and attractive π-stacking interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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