Highly emissive polymorphs of anhydrous cadmium tetracyanoplatinate and their solvated coordination networks-Reference-Cited by-同舟云学术

Highly emissive polymorphs of anhydrous cadmium tetracyanoplatinate and their solvated coordination networks

Published:2022 Issue:24 Volume:51 Page:9531-9540
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sergeenko Ania S.¹^ORCID,Paripovic Damir¹,Dab Chahinez²^ORCID,Blanc Pierre-François²,Reber Christian²^ORCID,Leznoff Daniel B.¹^ORCID

Affiliation:

1. Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, V5A 1S6, Canada

2. Département de chimie, Université de Montréal, C.P. 6128 Succ. Centre-ville, Montréal, QC H3C 3J7, Canada

Abstract

The α- and β-polymorphs of Cd[Pt(CN)4] are densely packed 3-D coordination polymers with quantum yields of 0.85 and 0.79. They react with donor solvent vapours to give emissive 2-D CdL2[Pt(CN)4] (L = DMSO, DMF, pyridine) cyanometallate sheets.

Funder

Fonds de recherche du Québec – Nature et technologies

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00918H

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5. Low-dimensional compounds containing cyano groups. XIV. Crystal structure, spectroscopic, thermal and magnetic properties of [CuL2][Pt(CN)4] complexes (L=ethylenediamine or N,N-dimethylethylenediamine)

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