Selective synthesis of iridium(iii) end-capped polyynes by oxidative addition of 1-iodopolyynes to Vaska's complex-Reference-Cited by-同舟云学术

Selective synthesis of iridium(iii) end-capped polyynes by oxidative addition of 1-iodopolyynes to Vaska's complex

Published:2018 Issue:47 Volume:47 Page:17046-17054
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pigulski Bartłomiej¹²³⁴^ORCID,Jarszak Agata¹²³⁴^ORCID,Szafert Sławomir¹²³⁴^ORCID

Affiliation:

1. Faculty of Chemistry

2. University of Wrocław

3. 50-383 Wrocław

4. Poland

Abstract

The reaction of bis(triphenylphosphine)iridium(i) carbonyl chloride (Vaska's complex) with a series of 1-iodopolyynes (1-C_nI and2-C_nI) gave σ-polyynyl iridium(iii) complexes with general formula R(CC)_nIr(PPh₃)₂(Cl)(I)(CO).

Funder

Narodowe Centrum Nauki

Fundacja na rzecz Nauki Polskiej

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT04219E

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