Why are <i>nH</i>-perfluoroalkanoate ions more mobile than expected? Implications for identifying an emerging environmental pollutant-Reference-Cited by-同舟云学术

Why are nH-perfluoroalkanoate ions more mobile than expected? Implications for identifying an emerging environmental pollutant

Published:2024 Issue:61 Volume:60 Page:7894-7897
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jobst Karl J.¹^ORCID,Penney Chloe¹,Burgers Peter C.²

Affiliation:

1. Department of Chemistry, Memorial University of Newfoundland, 45 Arctic Ave., St. John's A1C 5S7, NL, Canada

2. Department of Neurology, Erasmus Medical Center, Rotterdam, The Netherlands

Abstract

Ion mobility experiments reveal that nH-PFCAs have relatively small collision cross sections compared to their perfluorinated analogues. Theory and experiment agree that this is because nH-PFCA ions undergo internal hydrogen bridging.

Funder

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02762K

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