N-Alkoxyimidazolylidines (NOHCs): nucleophilic carbenes based on an oxidized imidazolium core-Reference-Cited by-同舟云学术

N-Alkoxyimidazolylidines (NOHCs): nucleophilic carbenes based on an oxidized imidazolium core

Published:2022 Issue:10 Volume:58 Page:1538-1541
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bakhonsky Vladyslav V.¹²^ORCID,Becker Jonathan³,Mlostoń Grzegorz⁴^ORCID,Schreiner Peter R.¹^ORCID

Affiliation:

1. Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17,, 35392 Giessen, Germany

2. Department of Organic Chemistry, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Prosp. Peremohy 37, 03056 Kyiv, Ukraine

3. Institute of Inorganic and Analytical Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Giessen, Germany

4. Department of Organic and Applied Chemistry, University of Łódź, Tamka 12, PL-91-403 Łódź, Poland

Abstract

Finally made: N-alkoxyimidazolylidenes (NOHCs), a new class of nucleophilic carbenes. The Arduengo-type analogous carbene center shows the most upfield 13C NMR shift compared to common NHCs.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05696D

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