Vibrational circular dichroism towards asymmetric catalysis: chiral induction in substrates coordinated with copper(ii) ions-Reference-Cited by-同舟云学术

Vibrational circular dichroism towards asymmetric catalysis: chiral induction in substrates coordinated with copper(ii) ions

Published:2020 Issue:42 Volume:22 Page:24393-24398
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sato Hisako¹²³⁴^ORCID,Takimoto Kazuyoshi¹²³⁴^ORCID,Yoshida Jun⁵⁶⁷⁴^ORCID,Yamagishi Akihiko⁸⁹¹⁰⁴

Affiliation:

1. Graduate School of Science and Engineering

2. Ehime University

3. Matsuyama 790-8577

4. Japan

5. Department of Chemistry

6. Kitasato University

7. Sagamihara 252-0329

8. School of Medicine

9. Toho University

10. Tokyo 143-8540

Abstract

The VCD method was applied for searching the origin of chirality selection in the asymmetric catalysis by Cu(ii) complexes. When 1-phenyl-1,3-butanedionato was coordinated, it was transformed to a twisted chiral form under the steric control.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP04827E

Reference46 articles.

1. Optically Active Organometallic Compounds of Transition Elements with Chiral Metal Atoms

2. Chiral Bis(oxazoline) Copper(II) Complexes: Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions

3. Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels−Alder Reaction

4. Enantioselective Synthesis of Dihydropyrans. Catalysis of Hetero Diels−Alder Reactions by Bis(oxazoline) Copper(II) Complexes

5. Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters

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