Gold-catalyzed (4 + 2)-annulations between α-alkyl alkenylgold carbenes and benzisoxazoles with reactive alkyl groups

Author:

Mokar Bhanudas Dattatray12345,Jadhav Prakash D.12345,Pandit Y. B.12345,Liu Rai-Shung12345ORCID

Affiliation:

1. Frontier Research Centers for Materials Science and Technology

2. Department of Chemistry

3. National Tsing-Hua University

4. Hsinchu

5. Republic of China

Abstract

This work reports new (4 + 2)-annulations of α-alkyl vinylgold carbenes with benzisoxazoles to afford 3,4-dihydroquinoline derivatives with high anti-stereoselectivity.

Funder

Ministry of Education

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference61 articles.

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2. Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

3. Catalytic Carbene Insertion into C−H Bonds

4. Vinyldiazo Reagents and Metal Catalysts: A Versatile Toolkit for Heterocycle and Carbocycle Construction

5. Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

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