Photoelectrochemical reduction of CO<sub>2</sub> catalyzed by a 3D core–shell NiMoO<sub>4</sub>@ZnO heterojunction with bicentre at the (111) plane and thermal electron assistance-Reference-Cited by-同舟云学术

Photoelectrochemical reduction of CO₂ catalyzed by a 3D core–shell NiMoO₄@ZnO heterojunction with bicentre at the (111) plane and thermal electron assistance

Published:2023 Issue:8 Volume:11 Page:4230-4237
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Cao Youzhi¹,Wei Yan¹,Wan Wenrui¹,Liu Chunyan¹,Zhuang Changwan¹,Gong Can¹,Nan Linhong¹,Zhang Qiaolan¹,Gao Hong¹,Chen Jiazang²^ORCID,Jing Huanwang¹²^ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou, 730000, PR China

2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, PR China

Abstract

The new mechanism of PEC reduction of CO2 on the bicentric catalyst is proven by DFT calculations and verified by the operando FTIR spectra, in which, the important intermediate of *OCH2 could connect each other for C2 products.

Funder

Natural Science Foundation of Gansu Province

State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09055D

Reference62 articles.

1. Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts