Bicyclic (alkyl)(amino)carbene stabilized zinc(0) complex with singlet biradicaloid ground state-Reference-Cited by-同舟云学术

Bicyclic (alkyl)(amino)carbene stabilized zinc(0) complex with singlet biradicaloid ground state

Published:2021 Issue:43 Volume:57 Page:5282-5285
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Rajendran N. M.¹²³⁴^ORCID,Gautam Nimisha¹²³⁴^ORCID,Sarkar Pallavi⁵⁶⁷⁴,Ahmed Jasimuddin¹²³⁴^ORCID,Das Arpan¹²³⁴^ORCID,Das Shubhajit⁵⁶⁷⁴^ORCID,Pati Swapan K.⁵⁶⁷⁴^ORCID,Mandal Swadhin K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Sciences

2. Indian Institute of Science Education and Research Kolkata

3. Mohanpur 741246

4. India

5. Theoretical Sciences Unit

6. Jawaharlal Nehru Centre For Advanced Scientific Research

7. Bangalore 560064

Abstract

The first Zn(0) complex bearing a bicyclic (alkyl)(amino)carbene ligand was synthesised and its reducing ability was demonstrated by activating the C–Cl bond of trityl chloride generating Gomberg's free radical at ambient temperature.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Jawaharlal Nehru Centre for Advanced Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01298C

Reference26 articles.

1. CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap

2. The Measure of All Rings-N-Heterocyclic Carbenes

3. An overview of N-heterocyclic carbenes

4. Stereoelectronic Chameleons: The Donor–Acceptor Dichotomy of Functional Groups

5. Silicon based radicals, radical ions, diradicals and diradicaloids

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