Gauging the donor strength of iron(0) complexes <i>via</i> their N-heterocyclic carbene gold(<scp>i</scp>) adducts-Reference-Cited by-同舟云学术

Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts

Published:2022 Issue:93 Volume:58 Page:12947-12950
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Toh Zhi Hao¹,Tinnermann Hendrik¹,Do Dinh Cao Huan¹^ORCID,Huynh Han Vinh¹^ORCID,Krämer Tobias²^ORCID,Young Rowan D.¹^ORCID

Affiliation:

1. Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore

2. Department of Chemistry, Maynooth University, Maynooth, Co. Kildare, Ireland

Abstract

We isolate and characterize the gold(i)–iron(0) adducts [(iPr2-bimy)Au–Fe(CO)3(PMe3)2][BArF4] and [Au–{Fe(CO)3(PMe3)2}2][BArF4] (iPr2-bimy = 1,3-diisopropylbenzimidazolin-2-ylidene, BArF4 = tetrakis(pentafluorophenyl)borate).

Funder

Agency for Science, Technology and Research

Irish Centre for High-End Computing

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC05041B

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