Synthesis and functionalization of the six-vertex anionic amido-substituted silicon cluster [Si6{N(SiMe3)Ph}5]−-Reference-Cited by-同舟云学术

Synthesis and functionalization of the six-vertex anionic amido-substituted silicon cluster [Si₆{N(SiMe₃)Ph}₅]⁻

Published:2023 Issue:41 Volume:52 Page:14949-14955
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Helmer Joschua¹,Hepp Alexander¹,Berger Raphael J. F.²,Lips Felicitas¹^ORCID

Affiliation:

1. Westfälische Wilhelms-Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstraße 28-30, 48149 Münster, Germany

2. Paris Lodron Universität Salzburg, Materialchemie, Jakob-Harringerstr. 2a, 5020 Salzburg, Austria

Abstract

Reaction of the amido-substituted silicon cluster Si6{N(SiMe3)Ph}6 1 with two equiv. of KC8 results in the anionic silicon cluster [Si6{N(SiMe3)Ph}5]— 2 that reacts with MeI, SiCl4 and SiBr4 to neutral double functionalized silicon clusters.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03952D

Reference41 articles.

1. Conjugated Polymers Inspired by Crystalline Silicon

2. Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials

3. Narrow bandgap colloidal metal chalcogenide quantum dots: synthetic methods, heterostructures, assemblies, electronic and infrared optical properties

4. Functionalization and post-functionalization: a step towards polyoxometalate-based materials

5. Modern cluster design based on experiment and theory

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