Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(i) dimers-Reference-Cited by-同舟云学术

Reduction of tert-butylphosphaalkyne and trimethylsilylnitrile with magnesium(i) dimers

Published:2022 Issue:3 Volume:51 Page:898-903
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wilson Daniel W. N.¹^ORCID,Jones Dafydd D. L.²^ORCID,Smith Cory D.²,Mehta Meera³^ORCID,Jones Cameron²^ORCID,Goicoechea Jose M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Oxford, 12 Mansfield Rd, Oxford OX1 3TA, UK

2. School of Chemistry, Monash University, Wellington Rd, Clayton VIC 3800, Australia

3. Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

We describe the reactivity of magnesium(i) dimers, [(nacnac)Mg]2 towards phosphaalkynes and Me3SiCN in an effort to understand how steric bulk influences the outcome of these reduction processes.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03990C

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