Anchored complexes of rhodium and iridium for the hydrogenation of alkynes and olefins with parahydrogen-Reference-Cited by-同舟云学术

Anchored complexes of rhodium and iridium for the hydrogenation of alkynes and olefins with parahydrogen

Published:2022 Issue:10 Volume:12 Page:3247-3253
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Skovpin Ivan V.¹,Kovtunova Larisa M.¹²,Nartova Anna V.²^ORCID,Kvon Ren I.²,Bukhtiyarov Valerii I.²^ORCID,Koptyug Igor V.¹^ORCID

Affiliation:

1. International Tomography Center, SB RAS, 3A Institutskaya St., Novosibirsk 630090, Russia

2. Boreskov Institute of Catalysis, SB RAS, 5 Acad. Lavrentiev Pr., Novosibirsk 630090, Russia

Abstract

Iridium and rhodium complexes anchored on silica gel surface via NH2–(CH2)3– and P(Ph)2–(CH2)2– linker groups achieve high (∼9%) efficiency in pairwise addition of parahydrogen to unsaturated gaseous substrates in heterogeneous hydrogenation processes.

Funder

Russian Foundation for Basic Research

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02258J

Reference50 articles.

1. D.Jeremic , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2014 , pp. 1–42

2. Catalytic hydrogenation of alkyne and alkadiene impurities from alkenes. Practical and theoretical aspects