Fluorescent organo-antimony compounds as precursors for syntheses of redox-active trimeric and dimeric alkali metal antimonides: an insight into electron transfer reduction processes-Reference-Cited by-同舟云学术

Fluorescent organo-antimony compounds as precursors for syntheses of redox-active trimeric and dimeric alkali metal antimonides: an insight into electron transfer reduction processes

Published:2022 Issue:5 Volume:51 Page:1791-1805
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nag Ekta¹^ORCID,Kulkarni Aditya¹^ORCID,Gorantla Sai Manoj N. V. T.²^ORCID,Graw Nico³^ORCID,Francis Maria¹^ORCID,Herbst-Irmer Regine³,Stalke Dietmar³^ORCID,Roesky Herbert W.³^ORCID,Mondal Kartik Chandra²^ORCID,Roy Sudipta¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati 517507, India

2. Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India

3. Institut für Anorganische Chemie, Georg-August-Universität, Tammannstraβe 4, 37077-Göttingen, Germany

Abstract

Fluorescent diarylchlorostibane, distibane are utilized as precursors for syntheses of redox-active dimeric/trimeric alkali-metal antimonides by reductive dehalogenation. DFT and EDA-NOCV analysis are performed to shed light on the electron transfer mechanism.

Funder

Council of Scientific and Industrial Research, India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03398K

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