Unbridged Rh(ii)–Rh(ii) complexes of N-heterocyclic carbenes and reactions with O2 to form dirhodium(μ–η1:η1-O2) complexes-Reference-Cited by-同舟云学术

Unbridged Rh(ii)–Rh(ii) complexes of N-heterocyclic carbenes and reactions with O2 to form dirhodium(μ–η1:η1-O2) complexes

Published:2019 Issue:12 Volume:48 Page:3835-3839
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yi Xiaofei¹²³⁴,Liu Bin⁵⁶⁴,Chen Kai¹²³⁴,Chen Wei¹²³⁴,Chen Wanzhi¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Zhejiang University

3. Hangzhou 310007

4. China

5. Zhejiang Province Key Laboratory of Noble Metal Catalytic Materials and Technology

6. Hangzhou

Abstract

Dimeric rhodium(ii) [Rh(L)(CH₃CN)]₂(PF₆)₄ and rhodium(iii) peroxide [Rh(L)(PPh₃)]₂(μ–η¹:η¹-O₂)(PF₆)₄ and [Rh(L)(PCy₃)]₂(μ–η¹:η¹-O₂)(PF₆)₄ (L = bis(N-pyridylimidazolylidenyl)methane) were reported.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00421A

Reference84 articles.

1. Reactions of Antitumor Active Dirhodium(II) Tetraacetate Rh2(CH3COO)4 with Cysteine and Its Derivatives

2. Interaction of [Rh2(O2CCH3)4(H2O)2] and [Rh2(O2CCH(OH)Ph)2(phen)2(H2O)2](O2C-CH(OH)Ph)2 With Sulfhydryl Compounds and Ceruloplasmin

3. Confocal Fluorescence Microscopy Studies of a Fluorophore-Labeled Dirhodium Compound: Visualizing Metal–Metal Bonded Molecules in Lung Cancer (A549) Cells

4. Live Cell Cytotoxicity Studies: Documentation of the Interactions of Antitumor Active Dirhodium Compounds with Nuclear DNA

5. Photophysical Properties, DNA Photocleavage, and Photocytotoxicity of a Series of Dppn Dirhodium(II,II) Complexes

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