Copper-catalyzed stereo- and regioselective hydrophosphorylation of terminal alkynes: scope and mechanistic study-Reference-Cited by-同舟云学术

Copper-catalyzed stereo- and regioselective hydrophosphorylation of terminal alkynes: scope and mechanistic study

Published:2022 Issue:29 Volume:12 Page:18889-18896
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Junchen¹,Gao Zhenhua¹,Guo Yongbiao¹^ORCID,Liu Haibo¹,Zhao Peichao¹,Bi Xiaojing¹,Shi Enxue¹^ORCID,Xiao Junhua¹^ORCID

Affiliation:

1. State Key Laboratory of NBC Protection for Civilian, Beijing, P. R. China

Abstract

A highly selective hydrophosphorylation of terminal alkynes was developed for the preparation of E-alkenylphosphorus compounds. Mechanistic investigations disclosed the deprotonation–protonation equilibrium of terminal alkynes and P(O)H compounds during this process.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA02908A

Reference43 articles.

1. Handbook of Organophosphorus Chemistry , ed R. Engel , Marcel Dekker, Inc. , New York , 1992

2. The Chemistry of Organophosphorus Compounds Vol. 4 , ed F. R. Hartley , John Wiley & Sons , Chichester , 1996

3. L. D.Quin , A Guide to Organophosphorus Chemistry , Wiley Interscience , New York , 2000

4. D. E. C.Corbridge , Phosphorus: Chemistry, Biochemistry and Technology , CRC Press , London , Sixth Edition, 2013

5. Phosphonate Biochemistry

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