Direct hydroxylation of benzene and aromatics with H2O2 catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism-Reference-Cited by-同舟云学术

Direct hydroxylation of benzene and aromatics with H2O2 catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism

Published:2017 Issue:23 Volume:7 Page:5677-5686
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Capocasa Giorgio¹²³⁴⁵,Olivo Giorgio¹²³⁴⁵,Barbieri Alessia¹²³⁴⁵,Lanzalunga Osvaldo¹²³⁴⁵^ORCID,Di Stefano Stefano¹²³⁴⁵^ORCID

Affiliation:

1. Dipartimento di Chimica

2. Università degli Studi di Roma “La Sapienza” and Istituto CNR di Metodologie Chimiche (IMC-CNR)

3. Sezione Meccanismi di Reazione

4. c/o Dipartimento di Chimica

5. Università degli Studi di Roma “La Sapienza”

Abstract

An imine-based catalyst easily obtained by self-assembly of cheap and commercially available starting materials selectively catalyzes the hydroxylation of aromatic compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY01895A

Reference69 articles.

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5. Aromatic hydroxylation by fenton reagents {Reactive intermediate[Lx+FeIIIOOH(BH+)], not free hydroxyl radical (HO·)}

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