Azeotrope enabled polymerization of ethylene oxide
Author:
Affiliation:
1. Institute of Materials Science
2. Polymer Program
3. University of Connecticut
4. USA
5. Department of Chemistry
Abstract
We report a synthetic route for poly(ethylene oxide) (PEO) using azeotropic distillation to remove water and drive the equilibrium of an alkyl hydroxide and potassium hydroxide to potassium alkoxide, avoiding the use of pyrophoric organometallics.
Funder
Division of Graduate Education
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22064A
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4. Synthesis and Characterization of Polystyrene-b-poly(ethylene oxide)-b-poly(ε-caprolactone) Block Copolymers
5. Poly(ethylene oxide)poly(propylene oxide)poly(ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling
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