Azeotrope enabled polymerization of ethylene oxide-Reference-Cited by-同舟云学术

Azeotrope enabled polymerization of ethylene oxide

Published:2016 Issue:97 Volume:6 Page:94459-94466
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bento Jennifer L.¹²³⁴,Madugula Drona R.⁵³⁴,Hire Chetan C.¹²³⁴,Adamson Douglas H.¹²³⁴⁵

Affiliation:

1. Institute of Materials Science

2. Polymer Program

3. University of Connecticut

4. USA

5. Department of Chemistry

Abstract

We report a synthetic route for poly(ethylene oxide) (PEO) using azeotropic distillation to remove water and drive the equilibrium of an alkyl hydroxide and potassium hydroxide to potassium alkoxide, avoiding the use of pyrophoric organometallics.

Funder

Division of Graduate Education

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22064A

Reference35 articles.

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2. Molecular design, synthesis and properties of block and graft copolymers containing polyoxyethylene segments

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4. Synthesis and Characterization of Polystyrene-b-poly(ethylene oxide)-b-poly(ε-caprolactone) Block Copolymers

5. Poly(ethylene oxide)poly(propylene oxide)poly(ethylene oxide) block copolymer surfactants in aqueous solutions and at interfaces: thermodynamics, structure, dynamics, and modeling

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