73Ge, 119Sn and 207Pb: general cooperative effects of single atom ligands on the NMR signals observed in tetrahedral [MXnY4−n] (M = Ge, Sn, Pb; 1 ≤ n ≤ 4; X, Y = Cl, Br, I) coordination compounds of heavier XIV group elements-Reference-Cited by-同舟云学术

73Ge, 119Sn and 207Pb: general cooperative effects of single atom ligands on the NMR signals observed in tetrahedral [MXnY4−n] (M = Ge, Sn, Pb; 1 ≤ n ≤ 4; X, Y = Cl, Br, I) coordination compounds of heavier XIV group elements

Published:2017 Issue:9 Volume:46 Page:2855-2860
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Benedetti M.¹²³⁴^ORCID,De Castro F.¹²³⁴,Fanizzi F. P.¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali

2. Università del Salento

3. I-73100 Lecce

4. Italy

Abstract

An inverse linear relationship between ⁷³Ge, ¹¹⁹Sn and ²⁰⁷Pb NMR chemical shifts and the sum of ionic radii of coordinated halides has been found in [MX_nY_m] (M = Ge, Sn, Pb; n + m = 4; X, Y = Cl, Br, I) compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00307B

Reference45 articles.

1. 73 Ge Nuclear Magnetic Resonance Studies

2. Nuclear magnetic resonance coupling constants in tin in 3,3,3-trifluoropropyltin compounds

3. 207Pb-NMR Parameters

4. G73e Nuclear Magnetic Resonance Spectroscopy of Germanium Compounds

5. NMR espectroscopic parameters of HX and Si(Sn)X4 (X=H, F, Cl, Br and I) and SnBr4−nIn model compounds

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