Water–gas shift reaction co-catalyzed by polyoxometalate (POM)–gold composites: the “magic” role of POMs-Reference-Cited by-同舟云学术

Water–gas shift reaction co-catalyzed by polyoxometalate (POM)–gold composites: the “magic” role of POMs

Published:2020 Issue:24 Volume:10 Page:8219-8229
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Lang Zhongling¹²³⁴⁵^ORCID,Li Yangguang¹²³⁴⁵^ORCID,Clotet Anna⁶⁷⁸⁹^ORCID,Poblet Josep M.⁶⁷⁸⁹^ORCID

Affiliation:

1. Key Laboratory of Polyoxometalate Science of the Ministry of Education

2. Faculty of Chemistry

3. Northeast Normal University

4. Changchun

5. China

6. Departament de Química Física i Inorgànica

7. Universitat Rovira i Virgili

8. 43007 Tarragona

9. Spain

Abstract

We computationally investigated the WGSR mechanism on POM supported gold and revealed the role of POMs. A direct pathway by formation of COOH_ads from the co-adsorbed H₂O and CO is proposed.

Funder

National Natural Science Foundation of China

Generalitat de Catalunya

Ministerio de Ciencia e Innovación

China Postdoctoral Science Foundation

Institució Catalana de Recerca i Estudis Avançats

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01722A

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