One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts

Author:

Ogawa Mana1,Usami Sayaka1,Takahama Ryo1,Iwamoto Kazuko1,Nabeta Tomomi1,Kawashima Shin2,Kojima Ryoichi2,Ohyama Junya3ORCID,Hayakawa Teruaki4ORCID,Nabae Yuta4ORCID,Moriya Makoto156ORCID

Affiliation:

1. Department of Science, Graduate School of Integrated Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan

2. Corporate Research & Development, Asahi Kasei Corporation, 2767-11 Niihama, Shionasu, Kojima, Kurashiki, Okayama 711-8510, Japan

3. Faculty of Advanced Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

4. Department of Materials Science and Engineering, Tokyo Institute of Technology, 2-12-1 S8-26, Ookayama, Meguro-ku, Tokyo 152-8552, Japan

5. College of Science, Academic Institute, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan

6. Research Institute of Green Science and Technology, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan

Abstract

MN4-type complexes with a 14-membered ring hexaazamacrocycle ligand were synthesised via a one-pot, gram-scale synthesis procedure using microwave heating for only 10 min.

Funder

New Energy and Industrial Technology Development Organization

Shizuoka University

Publisher

Royal Society of Chemistry (RSC)

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