Structure–property-reactivity studies on dithiaphospholes-Reference-Cited by-同舟云学术

Structure–property-reactivity studies on dithiaphospholes

Published:2019 Issue:45 Volume:48 Page:16922-16935
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ould Darren M. C.¹²³⁴⁵,Tran Thao T. P.⁶⁷⁸⁹,Rawson Jeremy M.⁶⁷⁸⁹^ORCID,Melen Rebecca L.¹²³⁴⁵^ORCID

Affiliation:

1. Cardiff Catalysis Institute

2. School of Chemistry

3. Cardiff University

4. Cymru/Wales

5. UK

6. Department of Chemistry and Biochemistry

7. University of Windsor

8. Windsor

9. Canada

Abstract

The crystal structures of P-halo-1,2,3-dithiaphospholes and the reduced P–P coupled dimer are reported. Treatment with Lewis acids affords phosphenium cations which are shown to be active catalysts for hydroboration reactions.

Funder

Engineering and Physical Sciences Research Council

Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03577J

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