Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions-Reference-Cited by-同舟云学术

Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions

Published:2023 Issue:30 Volume:59 Page:4527-4530
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Panda Surajit¹^ORCID,Nanda Amareshwar¹^ORCID,Behera Rakesh R.¹,Ghosh Rahul¹,Bagh Bidraha¹^ORCID

Affiliation:

1. School of Chemical Sciences, National Institute of Science Education and Research (NISER), An OCC of Homi Bhabha National Institute, Bhubaneswar, Jatni, Khurda, Odisha, PIN 752050, India

Abstract

Cobalt-catalyzed hydrosilylation of nitroarenes is reported for the first time using commercially available Co2(CO)8 under thermal and photochemical conditions. The scope of this protocol was significantly expanded including drug synthesis.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00328K

Reference48 articles.

1. S. A.Lawrence , Amines: synthesis, properties and applications , Cambridge University Press , 2004

2. Z.Rappoport , The Chemistry of Anilines , Wiley-VCH , Weinheim , 2007

3. Reduction of Organic Compounds by Lithium Aluminum Hydride. III. Halides, Quinones, Miscellaneous Nitrogen Compounds1

4. Reduction of aromatic nitro compounds with sodium borohydride in dimethyl sulfoxide or sulfolane. Synthesis of azo or azoxy derivatives

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