High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu3BTC2 micropores

Author:

Schneider Christian1234ORCID,Ukaj Dardan1234ORCID,Koerver Raimund56784,Talin A. Alec91011,Kieslich Gregor1234ORCID,Pujari Sidharam P.12131415ORCID,Zuilhof Han1213141516ORCID,Janek Jürgen56784ORCID,Allendorf Mark D.91011ORCID,Fischer Roland A.1234ORCID

Affiliation:

1. Department of Chemistry

2. Technical University Munich

3. 85748 Garching

4. Germany

5. Institute of Physical Chemistry

6. Center for Materials Research (ZFM)

7. Justus-Liebig-University Giessen

8. 35392 Giessen

9. Sandia National Laboratories

10. Livermore

11. USA

12. Laboratory of Organic Chemistry

13. Wageningen University & Research

14. 6708 WE Wageningen

15. The Netherlands

16. School of Pharmaceutical Sciences and Technology

Abstract

The host–guest system TCNQ@Cu3BTC2 is a striking example of how semiconductivity can be introduced by guest incorporation in an otherwise insulating parent material.

Funder

Deutscher Akademischer Austauschdienst

Laboratory Directed Research and Development

Verband der Chemischen Industrie

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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