Photoelectrochemical C–H activation of methane to methyl radical at room temperature

Author:

Amano Fumiaki1ORCID,Shintani Ayami2,Sakakura Tatsuya3,Takatsuji Yoshiyuki3,Haruyama Tetsuya3ORCID

Affiliation:

1. Department of Applied Chemistry for Environment, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan

2. Department of Chemical and Environmental Engineering, The University of Kitakyushu, 1-1 Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka 808-0135, Japan

3. Department of Biological Functions and Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu-ku, Kitakyushu, Fukuoka, 808-0196, Japan

Abstract

Visible light illumination induced CH4oxidation over a WO3photoanode. The production of C2H6implies the formation of methyl radicals through photoelectrochemical activation of methane.

Funder

Japan Society for the Promotion of Science

Precursory Research for Embryonic Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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