Geometry and electronic structure of Yb(<scp>iii</scp>)[CH(SiMe3)2]3 from EPR and solid-state NMR augmented by computations-Reference-Cited by-同舟云学术

Geometry and electronic structure of Yb(iii)[CH(SiMe₃)₂]₃ from EPR and solid-state NMR augmented by computations

Published:2024 Issue:11 Volume:26 Page:8734-8747
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ashuiev Anton¹,Allouche Florian¹,Islam Md. Ashraful²^ORCID,Carvalho José P.³^ORCID,Sanders Kevin J.²^ORCID,Conley Matthew P.⁴^ORCID,Klose Daniel¹^ORCID,Lapadula Giuseppe¹,Wörle Michael¹,Baabe Dirk⁵,Walter Marc D.⁵^ORCID,Pell Andrew J.²^ORCID,Copéret Christophe¹^ORCID,Jeschke Gunnar¹,Pintacuda Guido²^ORCID,Andersen Richard A.⁶

Affiliation:

1. Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1-5, 8093 Zurich, Switzerland

2. Université de Lyon, Centre de RMN à Très Hauts Champs de Lyon (UMR 5082 - CNRS, ENS Lyon, Université Claude Bernard Lyon 1), F-69100 Villeurbanne, France

3. Department of Materials and Environmental Chemistry, Stockholm University, Svänte Arrhenius väg 16 C, 106 91 Stockholm, Sweden

4. Department of Chemistry and Chemical Sciences, University of California Riverside, 501 Big Springs Road, Riverside, CA 92521, USA

5. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

6. Department of Chemistry, University of California, Berkeley, CA 94720, USA

Abstract

The combined use of magnetic resonance spectroscopies (EPR and solid-state NMR) and computational approaches enable the determination of the electronic structure and geometry of a paramagnetic Yb(iii) alkyl complex.

Funder

Agence Nationale de la Recherche

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00281D

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