Effective corrosion inhibition of mild steel in hydrochloric acid by newly synthesized Schiff base nano Co(ii) and Cr(iii) complexes: spectral, thermal, electrochemical and DFT (FMO, NBO) studies

Author:

Melhi Saad1,Bedair Mahmoud A.23ORCID,Alosaimi Eid H.1,Younes Ayman A. O.1,El-Shwiniy Walaa H.14ORCID,Abuelela Ahmed M.3

Affiliation:

1. Department of Chemistry, College of Science, University of Bisha, P.O. Box 511, Bisha 61922, Saudi Arabia

2. College of Science and Arts, University of Bisha, P.O. Box 101, Al-Namas 61977, Saudi Arabia

3. Department of Chemistry, Faculty of Science (Men's Campus), Al-Azhar University, Nasr City 11884, Cairo, Egypt

4. Department of Chemistry, Faculty of Science, Zagazig University, Zagazig 44519, Egypt

Abstract

Two Co(ii) and Cr(iii) complexes were synthesized, characterized and examined as corrosion inhibitors. The electrochemical data showed high inhibition efficiencies with mixed-type behavior. FMO and NBO were considered for the computational analysis.

Funder

University of Bisha

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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