In situ tailoring bimetallic–organic framework-derived yolk–shell NiS2/CuS hollow microspheres: an extraordinary kinetically pseudocapacitive nanoreactor for an effective sodium-ion storage anode

Author:

Zhao Wenxi12345,Wang Xiaodeng6784,Ma Xiaoqing1234ORCID,Yue Luchao59104,Liu Qian1112104ORCID,Luo Yonglan1112104ORCID,Liu Yang1314154,Asiri Abdullah M.1617181920ORCID,Sun Xuping59104ORCID

Affiliation:

1. School of Electronic Information Engineering

2. Yangtze Normal University

3. Chongqing

4. China

5. Institute of Fundamental and Frontier Sciences

6. College of Chemistry Environmental Engineering

7. Shenzhen University

8. Shenzhen

9. University of Electronic Science and Technology of China

10. Chengdu

11. Institute for Advanced Study

12. Chengdu University

13. School of Materials Science and Engineering

14. Henan Normal University

15. Xinxiang

16. Chemistry Department

17. Faculty of Science & Center of Excellence for Advanced Materials Research

18. King Abdulaziz University

19. Jeddah

20. Saudi Arabia

Abstract

Yolk–shell NiS2/CuS hollow microspheres as an extraordinary kinetically pseudocapacitive nanoreactor for sodium-ion batteries manifest superb Na+-storage capability, including an ultrahigh ICE of 94.0%, remarkable specific capacity of 410.9 mA h g−1 after 750 cycles at 2.0 A g−1, excellent rate capability, and prolonged cyclability in terms of a remarkable retention of 283.4 mA h g−1 even after 4200 cycles at 20.0 A g−1.

Funder

Natural Science Foundation of Chongqing

China Postdoctoral Science Foundation

Program for Innovation Team Building at Institutions of Higher Education in Chongqing

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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